I also found another note which I made while I was heavily following Unity code drops. If you are just targeting to WPF then this concept could also be another way to approach. Please note that this only will work on WPF not on Silverlight.
Anyhow Denis did a good experimental coding earlier on this subject and he walkthroughs and explains on his series how to do IoC Injection with Unity Application Block by using Markup Extensions.
If you want to get more flexibility in lower level this could be one way to solve it in your WF/WPF application. Again, you do need to do some experimental coding here as it’s not str8 forward but hopefully gives you some thoughts and ideas more.
See Denis series on link below:
http://dvuyka.spaces.live.com/blog/cns!305B02907E9BE19A!307.entry
Regards,
Alexander